Reactions of highly strained polycyclic compounds.

Chemistry of Strained Polycyclic Compounds —vi1,2

The base induced homoketonization of bridgehead cubane alcohol 10, homocubane alcohol 1 and acetate 7, and 1,3-bishomocubane alcohols 13 and 17 has been studied. Under protic conditions, homocubane alcohol 1 and acetate 7 are converted quantitatively into half cage ketones 3 and 8, respectively. by exclusive cleavage of the C4— C7 bond. Similarly, homoketonization of 1,3-bishomocubane alcohols ...

Chemistry of Strained Polycyclic Compounds —vi1,2

The base induced homoketonization of bridgehead cubane alcohol 10, homocubane alcohol 1 and acetate 7, and 1,3-bishomocubane alcohols 13 and 17 has been studied. Under protic conditions, homocubane alcohol 1 and acetate 7 are converted quantitatively into half cage ketones 3 and 8, respectively. by exclusive cleavage of the C4— C7 bond. Similarly, homoketonization of 1,3-bishomocubane alcohols ...

An efficient route to highly strained cyclobutenes: indium-catalyzed reactions of enynals with alkynes.

A catalytic method to synthesize the highly strained cyclobutene was developed. The reaction was believed to proceed through a formal indium-catalyzed [2+2] cycloaddition between electron-deficient enynals and various alkynes.

Non-linear electro-elastic coupling in highly strained zinc-blende compounds: InGaP/GaP [111] quantum wells

Determination Functional Theory Investigation of Polyphenolic Compounds Reactions: NMR study

Over the past decade, the chemical behavior of flavonoids as antioxidants has become the subject ofintense experimental research. In this paper, we use a quantum-chemical approach to shed light on thereactivity of four poly phenols, Benzoic acid, vanilic acid, gallic acid and flavone . In order to establishthe most efficient theoretical methodology, different methods, either Hartree—Fock-based ...